• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    This invention relates to a method of making iron from iron ore by subjecting an iron oxide feedstock such as iron ore to a solid reduction with a reducing gas fed from a melt-reducing furnace (briefly sometimes "melting furnace") and then supplying the feedstock to the melting furnace for melt reduction thereof, more particularly a method capable of using a low grade fuel and maintaining and improving the reaction efficiency by applying various controls to evolved gas which is utilized in the reaction.
    公开号:SU1609456A3
    申请号:SU864027934
    申请日:1986-07-17
    公开日:1990-11-23
    发明作者:Аоки Мамору
    申请人:Кабусики Кайся Кобе Сейкосе (Фирма)；
    IPC主号:
    专利说明:


    OM
    The invention relates to coke-less metallurgy for the production of iron from iron ore5 by subjecting the mixture to iron oxides, such as iron ore, to reduction to solid state using a reducing agent supplied from a smelting reducing furnace, and then
    supplying the mixture to the smelting furnace for smelting reduction, where low-grade fuel can be used, to maintain and test the efficiency of the reaction due to various
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    nor the gas that is used in the reaction ..
    The purpose of the invention is to increase the efficiency of the process.
    FIG. 1 shows a flow chart of the proposed method and a device for its implementation; in fig. 2 and 3 - technological schemes with two-stage gas injection.
    The device contains a furnace 1 for the direct production of liquid metal by reducing iron ore, a pipe 2 at the outlet of the body of the smelting reduction furnace, a furnace 3
    for pre-reduction (shaft furnace), scrubber 5 for gas purification from CO and compressor 6.
    Example. The high-temperature reducing gas, a, formed in the smelting reducing furnace 1, is mixed with methane b to the exhaust pipe 2 of the melting furnace to produce a controlled reducing gas, which is cooled and controlled by a reforming reaction. A part of the reducing gas discharged from the shaft furnace 3 is cooled in the heat exchanger 4 and then introduced as cold gas 1 into the scrubber 5, in which
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    CO. The cooled gas can be compressed before it enters the scrubber 5. The purified gas is compressed in the compressor and then mixed as compressed gas d with gas c to produce a mixed gas e, which must be introduced into the shaft furnace 3. The mixed gas e is cooled and has a temperature suitable for its entry into the shaft furnace 3. In order to increase the effect of eliminating the formation of clusters, it is recommended to introduce methane g in an appropriate proportion (12.7% in this example) to the mixed reducing gas e and to introduce the resulting gaseous mixture Camping as gas f into the shaft furnace 3.
    B tab. Figure 1 shows an example of a balance based on the flow chart of the proposed method, in which the presented values are obtained by calculating the liquid metal output from a melting furnace of 400,000-500,000 tons / year.
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    The reducing gas at a high temperature of 1609 ° C and a flow rate of 2876 kg-mol / h coming out of the melting furnace is in contact with methane (339 kg-mol / h) in the outlet of the melting furnace and in the exhaust pipe, which allows reforming reaction. As a result, the physical heat of the reducing gas leaving the melting furnace is effectively used and, thus, cooling is achieved (1609 ° C
    1054 ° C)
    high-temperature reducing gas and an increase in the ratio (0.26 -5 0.43), and this reduces or eliminates heat loss, wear of the lining at the exit of the smelting furnace and in the discharge pipe, as well as prevent the formation of accumulations in the furnace for pre-reduction.
    Clusters can be eliminated as follows. Improving the ratio. in the reducing gas, which is introduced into the shaft furnace, and the formation of a carbon coating on the reduced iron with the help of added methane prevents the formation of clusters. The amount of methane needed to prevent the formation of clusters based on the reducing gas content is 12.7%.
    It is necessary to add methane to the reducing gas introduced into the shaft furnace, and therefore in the reforming reaction carried out by mixing high-temperature reducing gas a leaving the smelting furnace with heated methane b, it is not necessary to spend all methane in the reforming reaction, since - but so that the reaction is carried out in part. The methane concentration decreases from 10.5% (before the start of the reaction) to 6.7% (after reforming). This reforming reaction is carried out using the heat of a mixed gas. Methane heated to 557 ° C and high-temperature reducing gas () coming out of the melting furnace are mixed and the temperature of the resulting gas mixture becomes 1063 ° t, since the reforming reaction proceeds as endothermic.
    From this it follows that the temperature of the reducing gas decreases by 546 ° C under the action of mixing ha.
    call and reforming reaction. In addition, by mixing the gas recirculated from the shaft furnace to the reducing gas at a rate of 1,435 kg mol / h, it is possible to regulate
    injection profile (777 ° C), which is suitable for reducing iron ore.
    To prevent the formation of accumulations in the shaft furnace, methane is added at 557 ° C at a rate of 167 kg mol / h. As a result, the temperature and composition of the gas in the shaft furnace are adjusted to values that are acceptable for the reduction of iron ore (763 ° C, reduction value, 0 CH4 () 1,2) Recovery can be carried out satisfactorily without the formation of clusters.
    Example 2 In a process relating to a two-stage gas injection method, high-temperature reducing gas a formed in the smelting reducing furnace 1 is mixed with methane b in the outlet pipe 2 of the smelting reducing furnace, and as a result a controlled reducing gas c is formed, which cooled and adjusted by the reforming reaction. A portion of the reducing gas j exiting the shaft furnace 3 is cooled in the heat exchanger 4 and then introduced as cooled gas k into the scrubber 5 to remove the COg. Before its introduction into the scrubber 5, the cooled gas can be compressed. In addition, carbon dioxide-free gas can be compressed in compressor 6 and then mixed with BaTij as compressed gas d with gas c to produce mixed gas e, which will be introduced into the shaft furnace 3. The mixed gas e is cooled and has a temperature which is suitable for introducing gas into the saddle furnace 3. Then the mixed reducing gas e is divided into two parts and methane g is added to one of the parts 1 in an appropriate proportion of methane g, the result is reducing gas f, which is cooled and adjusted to those Temperatures for injecting gas from the top tuyere of a shaft furnace. Also, methane h is added to the remaining gas 12 in an appropriate proportion to produce reducing gas i, which is cooled and
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    they are guided to the injection temperature and reduction rate, which are suitable for the reforming reaction at the bottom of the pit furnace. Gas 1 is introduced in some cases separately without the inclusion of methane in it in the upper part of the reduction furnace as a reducing gas f.
    Since the gas is rich in CO, it can generate heat, which as a result of the partial reduction reaction in the shaft furnace leads to the formation of accumulations. To avoid this, methane is introduced into the reducing gas, and the reduced iron is coated with precipitated carbon.
    In tab. Figure 2 shows an example of a balance based on the technological scheme of the proposed method, in which the indicated values are obtained by calculating the yield of liquid metal from the melting furnace in units of 400,000-500,000 tons / year.
    The reducing gas at high temperature (2876 kg-mol / h) coming out of the smelting furnace is in contact with methane (339 kg mol / h) in the outlet of the smelting furnace and in the exhaust pipe, resulting in a reforming reaction.
    Thus, the physical heat of the reducing gas from the melting furnace is effectively used, whereby cooling (1596 C - 1061 C) of the high temperature reducing gas and increasing the ratio (O, 26, 43) H2 / CO is achieved and it becomes possible to reduce or eliminate heat loss, wear linings in the outlet of the smelting furnace and in the discharge pipe, as well as the avoidance of the formation of accumulations in the furnace for pre-reduction.
    The formation of clusters is hindered by an improved ratio in the reducing gas introduced into the shaft furnace, and the formation of a carbon coating on the reduced metal with the addition of methane. The amount of methane, to prevent accumulation, is about 10% sludge (varying amount and reducing content of gpz-m.
    In reducing gas turbines, into a shaft furnace, it is necessary to collect 1. methane and, consequently, to the refinery;:, 1, and reforming, lead wires; nocrc .ru TBOM mixing the high temperature reducing gas a leaving the melting furnace with heated methane b, it is not necessary to spend all of the methane, since it is desirable that this reaction be carried out partially. The methane concentration decreases from 10.5% (before reaction) to 6.7% (after reforming). This reforming reaction is carried out using the heat of a mixed gas. Methane (339 kgmol / h), heated to, and high-temperature reducing gas (2876 kg mol / h at 1596 ° C, produced from the melting furnace, are mixed, and the temperature of the resultant gas equals 1061 ° C when the reaction mixture reform10
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    Minga was performed as an endothermic reaction.
    From this it follows that the temperature of the reducing gas is reduced by 535 ° C under the action of the gases and the reforming reaction, in addition, by mixing the gas 25 recirculated from the shaft furnace with the reduction gas at a speed of 1714 kgmol / h.
    6094568
    rises to the top, a reforming reaction occurs. Near the top tuyere of the shaft furnace, the methane concentration decreases from 10.4% to 6.5%. The reduction rate is improved from 7.6 to 13.4 and a gas composition is obtained which is effective for reducing iron ore in the upper part of the shaft furnace. This reformed gas rises through the interior of the shaft furnace and is mixed with gas f of R 7.6 introduced from the upper tuyeres, whereby the value of .5 and the gas composition suitable for reducing iron ore is achieved. Thus, in the upper part, it became possible to produce normally reduced iron ore without the formation of clusters,
    In the process, referring to a two-stage injection method (Fig, 3), a high-temperature reducing gas, used in the melting furnace 1 with a reducing atmosphere, is mixed with methane in the exhaust pipe 2 of the melting-reducing 15
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    The temperature of the gas inlet to 75.5 ° C, of the boiler furnace and obtain an adjustable Torah is acceptable for the heating of the reducing gas (corresponding to the reformed gas), which is cooled and regulated as a result of the reforming reaction,
    Example 3, A portion of the reducing gas i, discharged from the shaft furnace 3, is cooled by means of a heat exchanger 4 and then introduced as cooled gas j into the scrubber 5 to remove CO. The cooled gas can be compressed before it enters the gas scrubber 5 carbon dioxide. The purified gas is compressed in compressor 6, then mixed in the form of compressed gas d with a part of gas c to obtain a mixed gas e, it is in a cooled state to a temperature suitable for its introduction into the shaft furnace 3, if necessary, methane g can be additionally mix with mixed gas. In this way, a reducing gas is obtained, which is cooled and adjusted to a temperature and degree of reduction suitable for entry from the upper tuyere of the shaft furnace. Gourd g is also added to the corresponding
    iron ore innovations.
    In order to eliminate the possibility of the formation of clusters, a methane deposit is added at a rate of 67 kgmol / h to a part of the reducing gas e, the temperature of which is Adjusted to, t, e, reducing gas 1 (2058 kg-mol / h) for entry into the top lance of the shaft furnace, whereby the temperature and composition of the gas in the lances of the shaft furnace are adjusted to values that are suitable for reducing iron ore, i.e., to a temperature of 743 s and the degree of reduction k | (CO + H2) (CO + t-H20), 6 now satisfactorily carried out the reaction without images or clusters.
    Moutane (100 kg-mol / h) is added to the branch for the remaining reducing gas 1 and the resulting mixture is introduced into the bottom lance of the shaft furnace. Such an injection gas has a temperature which corresponds to injection and has a composition of (CO2 +) 1.0 suitable for carrying out a partial reforming reaction in; The shaft furnace, where this gas is introduced; from the bottom tuyere of the shaft furnace and he
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    proportions to the remaining part h of the controlled reducing gas c and add part of the recycled proportion to the remaining part h of the regulated reducing gas c and add part of the recycled 91
    whereby getting
    go gas i
    The reducing gas is cooled and adjusted to the injection temperature and degree of reduction suitable for the reforming reaction in the lower part of the shaft furnace.
    Since the gas is rich in CO, heat can form as a result of the partial reduction reaction in the shaft furnace, therefore accumulation is possible. In order to eliminate this deficiency, methane is introduced into the reducing gas, and the reduced iron is covered by a wasp. carbon data.
    In tab. 3 shows an example of a balance based on the technological scheme of the proposed method, in which the indicated values are obtained by calculating the yield of liquid metal from the smelting furnace in units of 400,000-500,000 tons / year.
    The reducing gas at high temperature (1596 ° С; 2876 kg "mol / h leaving the melting furnace is in contact with methane (339 kg mol / h) in the outlet of the melting furnace and in the exhaust pipe, allowing the reforming reaction. As a result the physical high-temperature reducing gas forming in the melting furnace is used efficiently and cooling (1596 ° C - 1062 ° C) of high temperatures is achieved

    reducing gas, and also increases (0.26-0.43) ratio. Thus, it becomes possible to reduce or eliminate heat loss, wear the lining in the outlet of the smelting furnace and in the inlet furnace, as well as eliminate accumulation.
    The formation of accumulations is prevented by an improved ratio in the reducing gas introduced into the shaft furnace and the formation of a carbon coating on the reducing iron by the addition of methane. The amount of methane needed to prevent the formation of clusters is approximately 6.6% based on the content of the reducing gas.
    In the reducing gas introduced into the shaft furnace, it is necessary to add methane and, therefore, in the reforming reaction, carried out by mixing high-temperature heating.
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    The settling gas a that leaves the smelting furnace, with heated methane b, does not necessarily consume all of the methane in the reforming process (it is permissible for the reaction to take place partially). This reforming reaction is carried out using the heat of the mixed gases. Methane (339 kg-mol / h) heated to 580 ° C and a high-temperature reducing gas of 2876 kg mol / h at a temperature of 1596 ° C that leaves the melting furnace mix the temperature of the resulting gaseous mixture to decrease as the reforming reaction proceeds as endothermic.
    From this it follows that the temperature of the reducing gas decreases by 534 ° C as a result of mixing the gases and carrying out the reforming reaction. Due to the mixing of gas d recirculated from the shaft furnace to a part of the produced gas with a speed of 1101 kg mol / h, it is possible to control the gas injection temperature (743 ° C) and the R value of the degree of reduction (CO + H) / (, 0) 6, which are suitable for the reduction of iron ore. The reducing gas f is introduced to recover to the upper part of the 3b shaft furnace 3.
    A portion (1374 kg mol / h) of the remaining allotted controlled reducing gas with (1062 ° C) is mixed with gas i (936 kg mol / h) released from the shaft furnace 3, and methane (167 kg mol / h) is added , preheated to 580 ° C, then the resulting gaseous mixture is directed into the lance of the shaft furnace in the lower part of it. Such gas for injection j has a temperature of 830 ° C (2504 kgmol / h), which corresponds to those injection temperatures and has the composition (C0 + + H20) 0.67j, necessary for carrying out a partial reforming reaction inside the shaft furnace. When this gas is injected from the bottom tuyere of the shaft furnace and rises to its upper part, a reforming reaction occurs. Adjacent to the tuyere in the upper part of the shaft furnace, the degree of reduction R and concentration of methane reach values of 9.0 and 4.3%, respectively. The gas is then mixed with the f-value gas, 6, introduced from the upper tuyere, as a result, the value and concentration of methane become
    Responsibly, 8.2% and 5.5%, and the composition of the gas that can be used to reduce iron ore is taken into account. Thus, normally reduced iron ore without the formation of clusters can also be obtained in the upper part of the furnace.
    The reducing gas, which is formed in a furnace using less expensive fuel, can be improved. So that it has a temperature, composition and composition that is suitable for pre-reduction, in: the result can be reduced costs for the direct metal production process. the reductive smelting and at the same time to carry out the reduction reaction is stable and efficient.
    权利要求:
    Claims (6)
    [1]
    1. A method for directly producing iron, including the preliminary reduction of the iron ore charge in: the solid state in the preliminary reduction furnace, the subsequent; loading into the melting furnace and the additional recovery in the melt by supplying natural fuel and gaseous oxidant, ensuring its combustion over the surface of the melt, the removal of the waste gases from the melts of the reducing furnace, their cooling and supply to the preliminary reduction furnace, due to the fact that, in order to increase the Onomics of the process, the waste gas from the melt of the reduction furnace, before being fed into the pre-reduction furnace, is partially mixed at the exit from the furnace with a gaseous reducing agent,
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    high temperature, while the temperature of the gaseous mixture is maintained in the range of 1200-1550 ° C.
    [2]
    2. The method according to claim 1, characterized in that methane is used as a gaseous reducing agent.
    [3]
    3. Method according to paragraphs. I and 2, characterized in that the concentration of unreacted natural fuel in the reformed gas is maintained within 2-13%.
    [4]
    4. A method according to claim 1, characterized in that a portion of the waste gas from the pre-reduction furnace is cleaned of oxidizers, mixed with the reformed gas and fed to the lower part of the pre-reduction furnace.
    [5]
    5. A method according to claim .1, characterized in that a part of the exhaust gas from the pre-reduction furnace is cleaned of oxidizers, mixed with the reformed gas and a part is fed to the upper part
    pre-reduction furnaces
    and the second part of this gas is shifted with natural gas and fed to the lower part of the pre-reduction furnace.
    [6]
    6. Method pop. 1, characterized in that a portion of the waste gas from the pre-reduction furnace is cleaned of oxidizers, mixed with the reformed gas and fed to the upper part of the pre-reduction furnace, in addition, part of the raw exhaust gas
    from the pre-reduction furnace it is mixed with natural gas and reformed and fed to the bottom of the pre-reduction furnace.
    9ig.2
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    同族专利:
    公开号 | 公开日
    EP0209861A2|1987-01-28|
    CN1009561B|1990-09-12|
    CN86105271A|1987-04-01|
    DE3679006D1|1991-06-06|
    EP0209861A3|1987-12-02|
    AU582453B2|1989-03-23|
    AU6025686A|1987-01-22|
    EP0209861B1|1991-05-02|
    CA1284274C|1991-05-21|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    DE1234749B|1963-07-04|1967-02-23|E H Hermann Schenck Dr Ing Dr|Method and device for the production of liquid iron from iron ores using oil or natural gas as reducing agent|
    DE2401909C3|1974-01-16|1985-06-27|Fried. Krupp Gmbh, 4300 Essen|Process for the production of steel|
    US4235425A|1979-07-16|1980-11-25|Midrex Corporation|Impact bed gasifier-melter|
    NO155669C|1980-06-23|1987-05-06|Asea Ab|PROCEDURE FOR MANUFACTURING RAJJAR AND SYNTHESIC GAS.|
    DE3318005C2|1983-05-18|1986-02-20|Klöckner CRA Technologie GmbH, 4100 Duisburg|Process for making iron|
    DE3503493C2|1985-01-31|1987-10-22|Korf Engineering Gmbh, 4000 Duesseldorf, De|
    US4599120A|1985-02-25|1986-07-08|Brush Wellman Inc.|Processing of copper alloys|JPH079015B2|1985-07-19|1995-02-01|株式会社神戸製鋼所|Smelting reduction method for iron ore|
    SE458688B|1985-07-23|1989-04-24|Ips Interproject Service Ab|PROCEDURE AND ESTABLISHMENT FOR PREPARATION OF RAJAJARS FROM ANNUAL OXIDIC MATERIAL|
    US4995906A|1987-12-18|1991-02-26|Nkk Corporation|Method for smelting reduction of iron ore|
    US5542963A|1994-09-21|1996-08-06|Sherwood; William L.|Direct iron and steelmaking|
    AT406382B|1996-11-06|2000-04-25|Voest Alpine Ind Anlagen|METHOD FOR THE PRODUCTION OF IRON SPONGE BY DIRECTLY REDUCTION OF MATERIAL CONTAINING IRON OXIDE|
    EP1160338A1|2000-05-31|2001-12-05|DANIELI & C. OFFICINE MECCANICHE S.p.A.|Process to preheat and reduce directly reduced ironto be fed to an electric arc furnace |
    CN102051426B|2009-11-02|2012-08-22|贾会平|Method and device for smelting iron by reduction|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    JP60159256A|JPH0689385B2|1985-07-18|1985-07-18|Method for smelting reduction of iron ore by two-stage injection|
    JP60159255A|JPH0581641B2|1985-07-18|1985-07-18|
    JP60159254A|JPH0689384B2|1985-07-18|1985-07-18|Smelting reduction of iron ore by the two-stage injection method|
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